Product ID:SODIUM FLUORIDE
MSDS Date:07/18/1985
FSC:6810
NIIN:00N065005
MSDS Number: BZKXL

MALLINCKRODT

PARIS, KY 40362
US

Emergency Phone: 314-539-1600

Info Phone: 314-539-1600

Cage: ZA916

MALLINCKRODT SPECIALTY CHEMICALS CO

PHILLIPSBURG, NJ 08865 US

Telephone: 908-859-2151

Cage: 62910

SODIUM FLUORIDE (CERCLA)

CAS: 7681-49-4

RTECS: WB0350000

OSHA PEL 2.5 PPM (F)

ACGIH TLV: 2.5 MG (F/)M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

15 MINUTES LONGER. REFER TO OPTHALMOLOGIST AFTER

RTECS: 9999999ZZ

PREFERRED BECAUSE IT CAN CTL EMISSIONS OF CONTAMINANT

RTECS: 9999999ZZ

WORK AREA. PLEASE REFER TO ACGIH DOCUMENT "INDUS

RTECS: 9999999ZZ

GOGGLES AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL RAT): 80 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE CORR EFTS TO
RESP TRACT. SYMPS MAY INCL COUGHING, SORE THROAT & LABORED BRTHG.
MAY BE ABSORBED THRU INHAL OF DUST, SYMPS MAY PARALLEL THOSE FROM
INGEST EXPOS. INGEST:TOX! MAY CAU SE SALIVATION, NAUS, VOMIT, DIARR
& ABDOM PAIN. SYMPS OF WEAK, TREMORS, SHALLOW RESP, CARDOPEDAL
SPASM,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CONVLS, & COMA MAY FOLLOW. MAY CAUSE
BRAIN & KIDNEY DMG. DEATH MAY OCCUR FROM RESP PARAL. LETHAL DOSE
MAY BE 5-10 G. SKIN: CAUSES IRRIT W/REDNESS & PAIN. SOLNS ARE CORR.
EYE: IRRIT! MAY CAUS E IRRIT & SERIOUS EYE DMG. CHRONIC: RPTD
INGEST OF SML AMTS MAY CAUSE MOTTLING OF TEETH & BONE DMG
(OSTEOSCLEROSIS).
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF
BRTHG DFCLT, GIVE OXYGEN. CALL MD. INGEST: IF CONSCIOUS, IMMED GIVE
2 TBSPS OF MAGNESIUM SULFATE & GLASS OF WATER. REPEAT 3 TIMES.
FOLLOW W/ TWO TBSPS OF MILK OF MAGNESIA & GLASS OF WATER. REPEAT
THESE DOSAGES IN 10 MIN. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERS. GET MED ATTN IMMED. SKIN: REMOVE ANY CONTAM CLTHG. WIPE OFF
EXCESS (SUP DAT)

Extinguishing Media:IF INVOLVED IN A FIRE, USE WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD.

Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP
PERSONNEL REQUIRE PROTECTIVE CLOTHING AND RESPIRATORY PROTECTION
FROM DUST. SPILLS: PICK UP AND PLACE IN A SUITABLE CONTAINER FOR
RECLAMATION OR DISPOSAL IN A METHOD THAT DOES NOT GENERATE DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATHE DUST. KEEP CONTAINER
CLOSED. USE ONLY WITH ADEQUATE VENTILATION. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING.
Other Precautions:KEEP IN TIGHTLY CLOSED CONTAINER, STORED IN A COOL,
DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. SEPARATE
FROM ACIDS AND OXIDIZING MATERIALS.

Respiratory Protection:IF TLV IS EXCEEDED, A NIOSH/MSHA APPRVD
DUST/MIST RESP W/CHEM GOGGLES MAY BE WORN, IN GEN, UP TO 10 TIMES
THE TLV. CONSULT RESP SUPP FOR LIMITATIONS. ALTERNATIVELY, A
NIOSH/MSHA APPRVD SUPP-AIR FULL F ACEPIECE RESP/AIRLINED HOOD MAY
BE WORN.
Ventilation:SYSTEM OF LOC &/GEN EXHAUST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIM. LOCAL EXHAUST VENT IS GEN (ING 3)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS (ING 5)
Other Protective Equipment:WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB
COAT, APRON/COVERALLS. ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES
SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL.
Supplemental Safety and Health
FIRST AID PROC: FROM SKIN. WASH W/PLENTY OF SOAP & WATER FOR AT LEAST
15 MIN. APPLY BANDAGE SOAKED IN MILK OF MAGNESIA. GET MED ATTN
PROMPTLY. EYE: WASH W/PLENTY OF WATER FOR AT LEAST 15 MIN, LIFTING
LOWER & UPPER EYELIDS OCCAS. FOR PAIN, USE 2-3 DROPS OF 0.5%
PONTOCAINE IN EACH EYE. CONTINUE WASHING (ING 2)

Boiling Pt:B.P. Text:3092F,1700C
Melt/Freeze Pt:M.P/F.P Text:1819F,993C
Vapor Pres:1 @ 1971F
Spec Gravity:2 @ 106F
Solubility in Water:4 G/100 ML WATER
Appearance and Odor:WHITE CRYSTALS, ODORLESS

Stability Indicator/Materials to Avoid:YES
REACTS WITH ACIDS TO FORM HYDROGEN FLUORIDE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:EMITS TOXIC FUMES OF FLUORIDES AND
SODIUM OXIDE WHEN HEATED TO DECOMPOSITION.

Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE
DISPOSED IN A RCRA APPROVED HAZARDOUS WASTE FACILITY. SMALL AMOUNTS
OF RESIDUE MAY BE FLUSHED TO SEWER W/PLENTY OF WATER. REPORTABLE
QUANTITY: 1000 LBS. ENSURE COMPLIANCE W/LOCAL, STATE & FEDERAL
REGS.

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particular situation.